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Solvent Effects on the Selectivity of Palladium-Catalyzed Suzuki-Miyaura Couplings

The use of polar solvents MeCN or dimethylformamide (DMF) was previously shown to induce a selectivity switch in the Pd/P(t)Bu(3)-catalyzed Suzuki-Miyaura coupling of chloroaryl triflates. This phenomenon was attributed to the ability of polar solvents to stabilize anionic transition states for oxid...

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Publicat a:Isr J Chem
Autors principals: Reeves, Emily K., Bauman, Olivia R., Mitchem, Gunner B., Neufeldt, Sharon R.
Format: Artigo
Idioma:Inglês
Publicat: 2019
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7566783/
https://ncbi.nlm.nih.gov/pubmed/33071305
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ijch.201900082
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