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Solvent Effects on the Selectivity of Palladium-Catalyzed Suzuki-Miyaura Couplings
The use of polar solvents MeCN or dimethylformamide (DMF) was previously shown to induce a selectivity switch in the Pd/P(t)Bu(3)-catalyzed Suzuki-Miyaura coupling of chloroaryl triflates. This phenomenon was attributed to the ability of polar solvents to stabilize anionic transition states for oxid...
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| Publicado en: | Isr J Chem |
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| Autores principales: | , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2019
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7566783/ https://ncbi.nlm.nih.gov/pubmed/33071305 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ijch.201900082 |
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