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Copper-Catalyzed Trifluoromethylation of Alkyl Bromides
Copper oxidative addition into organo-halides is a challenging two-electron process. In contrast, formal oxidative addition of copper to C(sp)(2) carbon−bromine bonds can be accomplished by employing latent silyl radicals under photoredox conditions. This novel paradigm for copper oxidative addition...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7557108/ https://ncbi.nlm.nih.gov/pubmed/30983333 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b03024 |
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