Emergence of a New [NNN] Pincer Ligand via Si−H Bond Activation and β‐Hydride Abstraction at Tetravalent Cerium

The cerium(IV) pyrazolate complexes [Ce(Me(2)pz)(4)](2) and [Ce(Me(2)pz)(4)(thf)] initiate β‐hydride abstraction of the bis(dimethylsilyl)amido moiety, to afford a heteroleptic cerium(IV) species containing a dimethylpyrazolyl‐substituted silylamido ligand, namely [Ce(Me(2)pz)(3)(bpsa)] (bpsa=bis((3...

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Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Chemistry
Egile Nagusiak: Werner, Daniel, Bayer, Uwe, Schädle, Dorothea, Anwander, Reiner
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: John Wiley and Sons Inc. 2020
Gaiak:
Full Papers
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC7540680/
https://ncbi.nlm.nih.gov/pubmed/32239686
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000625
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