Iron(0)‐Mediated Stereoselective (3+2)‐Cycloaddition of Thiochalcones via a Diradical Intermediate

Reactions of α,β‐unsaturated aromatic thioketones 1 (thiochalcones) with Fe(3)(CO)(12) leading to η(4)‐1‐thia‐1,3‐diene iron tricarbonyl complexes 2, [FeFe] hydrogenase mimics 3, and the thiopyrane adduct 4 are described. Obtained products have been characterized by X‐ray crystallography and by comp...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Buday, Philipp, Seeber, Phillip, Zens, Clara, Abul‐Futouh, Hassan, Görls, Helmar, Gräfe, Stefanie, Matczak, Piotr, Kupfer, Stephan, Weigand, Wolfgang, Mloston, Grzegorz
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7540601/
https://ncbi.nlm.nih.gov/pubmed/32212185
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202001412
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