Iodination of cyclo‐E(5)‐Complexes (E=P, As)

In a high‐yield one‐pot synthesis, the reactions of [Cp*M(η(5)‐P(5))] (M=Fe (1), Ru (2)) with I(2) resulted in the selective formation of [Cp*MP(6)I(6)](+) salts (3, 4). The products comprise unprecedented all‐cis tripodal triphosphino‐cyclotriphosphine ligands. The iodination of [Cp*Fe(η(5)‐As(5))]...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Brake, Helena, Peresypkina, Eugenia, Virovets, Alexander V., Piesch, Martin, Kremer, Werner, Zimmermann, Lisa, Klimas, Christian, Scheer, Manfred
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2020
Matèries:
Research Articles
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7540426/
https://ncbi.nlm.nih.gov/pubmed/32463937
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202004812
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