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Calorimetric Signature of Deuterated Ice II: Turning an Endotherm to an Exotherm

[Image: see text] Calorimetric studies on ice II reveal a surprising H(2)O/D(2)O isotope effect. While the ice II to ice Ic transition is endothermic for H(2)O, it is exothermic for D(2)O samples. The transition enthalpies are +40 and −140 J/mol, respectively, where such a sign change upon isotope s...

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Detalhes bibliográficos
Publicado no:J Phys Chem Lett
Main Authors: Fuentes-Landete, Violeta, Rasti, Soroush, Schlögl, Robert, Meyer, Jörg, Loerting, Thomas
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2020
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7528406/
https://ncbi.nlm.nih.gov/pubmed/32902994
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpclett.0c02368
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