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Slowing Down of the Molecular Reorientation of Water in Concentrated Alkaline Solutions

[Image: see text] It is generally accepted that the hydroxide ion (OH(–)) is a strong hydrogen bond acceptor and that its anomalously high diffusion constant in water results from a Grotthuss-like structural diffusion mechanism. However, the spatial extent over which OH(–) ions influence the dynamic...

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Detalhes bibliográficos
Publicado no:J Phys Chem B
Main Authors: Cota, Roberto, van Dam, Eliane P., Woutersen, Sander, Bakker, Huib J.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2020
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7520889/
https://ncbi.nlm.nih.gov/pubmed/32841025
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpcb.0c03614
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