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Regio- and Stereoselective Synthesis of the Core Structure of Hexahydrobenzo[c]phenanthridine Alkaloids via Redox-Neutral Cp*Rh(III)-Catalyzed C–H/N–H Annulation of Cyclic Alkenes with Benzamides

[Image: see text] A highly stereo- and regioselective synthesis of the core skeleton of hexahydrobenzo[c]phenanthridine-type alkaloids is reported herein for the first time. A wide range of substrate scope, excellent functional group tolerance, and good to excellent yields were observed. This protoc...

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Detalhes bibliográficos
Publicado no:ACS Omega
Main Authors: Das Adhikari, Gopal Krushna, Chebolu, Rajesh, Ravikumar, Ponneri Chandrababu
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2020
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7513371/
https://ncbi.nlm.nih.gov/pubmed/32984725
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.0c03434
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