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Photochemical Ring Opening of Oxirane Modeled by Constrained Density Functional Theory

[Image: see text] A constrained density functional theory/classical trajectory surface hopping study of the photochemical dissociation of oxirane (CH(2))(2)O is presented. The calculations confirm the Gomer–Noyes mechanism for the initial reaction and agree largely with experimental photolysis data...

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Veröffentlicht in:ACS Omega
Hauptverfasser: Krenz, Marvin, Gerstmann, Uwe, Schmidt, Wolf Gero
Format: Artigo
Sprache:Inglês
Veröffentlicht: American Chemical Society 2020
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7513336/
https://ncbi.nlm.nih.gov/pubmed/32984727
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.0c03483
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