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Does the crystal structure of vanadium nitrogenase contain a reaction intermediate? Evidence from quantum refinement
ABSTRACT: Recently, a crystal structure of V-nitrogenase was presented, showing that one of the µ(2) sulphide ions in the active site (S2B) is replaced by a lighter atom, suggested to be NH or NH(2), i.e. representing a reaction intermediate. Moreover, a sulphur atom is found 7 Å from the S2B site,...
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| Publicado no: | J Biol Inorg Chem |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Springer Berlin Heidelberg
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7511287/ https://ncbi.nlm.nih.gov/pubmed/32856107 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00775-020-01813-z |
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