Stereochemical Inversion of Rim-Differentiated Pillar[5]arene Molecular Swings

[Image: see text] To investigate the dynamic stereochemical inversion behavior of pillar[5]arenes (P[5]s) in more detail, we synthesized a series of novel rim-differentiated P[5]s with various substituents and examined their rapid rotations by variable-temperature NMR (203–298 K). These studies reve...

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Detalhes bibliográficos
Publicado no:J Org Chem
Main Authors: Du, Ke, Demay-Drouhard, Paul, Samanta, Kushal, Li, Shunshun, Thikekar, Tushar Ulhas, Wang, Haiying, Guo, Minjie, van Lagen, Barend, Zuilhof, Han, Sue, Andrew C.-H.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2020
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7498154/
https://ncbi.nlm.nih.gov/pubmed/32820630
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.0c01464
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