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Enantiomerically Pure Tetravalent Neptunium Amidinates: Synthesis and Characterization
The synthesis of a tetravalent neptunium amidinate [NpCl((S)‐PEBA)(3)] (1) ((S)‐PEBA=(S,S)‐N,N′‐bis‐(1‐phenylethyl)‐benzamidinate) is reported. This complex represents the first structurally characterized enantiopure transuranic compound. Reactivity studies with halide/pseudohalides yielding [NpX((S...
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| Publicado no: | Chemistry |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7497184/ https://ncbi.nlm.nih.gov/pubmed/32347986 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202001865 |
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