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Rapid Organocatalytic Formation of Carbon Monoxide: Application towards Carbonylative Cross Couplings

Herein, the first organocatalytic method for the transformation of non‐derivatized formic acid into carbon monoxide (CO) is introduced. Formylpyrrolidine (FPyr) and trichlorotriazine (TCT), which is a cost‐efficient commodity chemical, enable this decarbonylation. Utilization of dimethylformamide (D...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Zoller, Ben, Zapp, Josef, Huy, Peter H.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7497008/
https://ncbi.nlm.nih.gov/pubmed/32516509
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202002746
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