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Intramolecular Reaction of Transient Phosphenium and Arsenium Ions Giving Rise to Isolable 9‐Phospha‐ and 9‐Arsena‐Fluorenium Ions

Transient phosphenium and arsenium ions, generated by fluoride abstraction from bis(m‐terphenyl)fluoropnictogens, underwent intramolecular electrophilic attack prior to methyl group migration and gave rise to isolable 9‐phospha‐ and 9‐arsena‐fluorenium ions.

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Olaru, Marian, Duvinage, Daniel, Naß, Yannik, Malaspina, Lorraine A., Mebs, Stefan, Beckmann, Jens
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7496934/
https://ncbi.nlm.nih.gov/pubmed/32460394
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202006728
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