A “Push–Pull” Stabilized Phosphinidene Supported by a Phosphine‐Functionalized β‐Diketiminato Ligand

The use of a bis(diphenyl)phosphine functionalized β‐diketiminato ligand, [HC{(CH(3))C}(2){(ortho‐[P(C(6)H(5))(2)](2)C(6)H(4))N}(2)](−) (PNac), as a support for germanium(II) and tin(II) chloride and phosphaketene compounds, is described. The conformational flexibility and hemilability of this uniqu...

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Vydáno v:Chemistry
Hlavní autoři: Bestgen, Sebastian, Mehta, Meera, Johnstone, Timothy C., Roesky, Peter W., Goicoechea, Jose M.
Médium: Artigo
Jazyk:Inglês
Vydáno: John Wiley and Sons Inc. 2020
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC7496897/
https://ncbi.nlm.nih.gov/pubmed/32511823
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202001762
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