Photocatalytic α‐Tertiary Amine Synthesis via C−H Alkylation of Unmasked Primary Amines

A practical, catalytic entry to α,α,α‐trisubstituted (α‐tertiary) primary amines by C−H functionalisation has long been recognised as a critical gap in the synthetic toolbox. We report a simple and scalable solution to this problem that does not require any in situ protection of the amino group and...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Ryder, Alison S. H., Cunningham, William B., Ballantyne, George, Mules, Tom, Kinsella, Anna G., Turner‐Dore, Jacob, Alder, Catherine M., Edwards, Lee J., McKay, Blandine S. J., Grayson, Matthew N., Cresswell, Alexander J.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Research Articles
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7496683/
https://ncbi.nlm.nih.gov/pubmed/32391968
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202005294
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