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Gold‐Catalyzed Cycloisomerization of Sulfur Ylides to Dihydrobenzothiepines

The metal‐promoted nucleophilic addition of sulfur ylides to π‐systems is a well‐established reactivity. However, the driving force of such transformations, elimination of a sulfide moiety, entails stoichiometric byproducts making them unfavorable in terms of atom economy. In this work, a new take o...

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Publicat a:Chemistry
Autors principals: Knittl‐Frank, Christian, Saridakis, Iakovos, Stephens, Thomas, Gomes, Rafael, Neuhaus, James, Misale, Antonio, Oost, Rik, Oppedisano, Alberto, Maulide, Nuno
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2020
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7496544/
https://ncbi.nlm.nih.gov/pubmed/32227380
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000622
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