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Transition‐Metal‐Free Oxidative Cross‐Coupling of Tetraarylborates to Biaryls Using Organic Oxidants

Readily prepared tetraarylborates undergo selective (cross)‐coupling through oxidation with Bobbitt's salt to give symmetric and unsymmetric biaryls. The organic oxoammonium salt can be used either as a stoichiometric oxidant or as a catalyst in combination with in situ generated NO(2) and mole...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Gerleve, Carolin, Studer, Armido
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7496537/
https://ncbi.nlm.nih.gov/pubmed/32159264
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202002595
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