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Aggregation and Degradation of White Phosphorus Mediated by N‐Heterocyclic Carbene Nickel(0) Complexes

The reaction of zerovalent nickel compounds with white phosphorus (P(4)) is a barely explored route to binary nickel phosphide clusters. Here, we show that coordinatively and electronically unsaturated N‐heterocyclic carbene (NHC) nickel(0) complexes afford unusual cluster compounds with P(1), P(3),...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Hierlmeier, Gabriele, Coburger, Peter, van Leest, Nicolaas P., de Bruin, Bas, Wolf, Robert
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2020
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7496536/
https://ncbi.nlm.nih.gov/pubmed/32348622
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202004020
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