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The Arachno‐Zintl Ion (Sn(5)Sb(3))(3−) and the Effects of Element Composition on the Structures of Isoelectronic Clusters: Another Facet of the Pseudo‐Element Concept

The pseudo‐element concept, in its most general formulation, states that isoelectronic atoms form equal numbers of bonds. Hence, clusters such as Zintl ions usually retain their structure upon isoelectronic replacement of some or all atoms. Here, a deviation from this common observation is presented...

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Vydáno v:Angew Chem Int Ed Engl
Hlavní autoři: Wilson, Robert J., Weigend, Florian, Dehnen, Stefanie
Médium: Artigo
Jazyk:Inglês
Vydáno: John Wiley and Sons Inc. 2020
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC7496391/
https://ncbi.nlm.nih.gov/pubmed/32449980
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202002863
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