A unified strategy to reverse-prenylated indole alkaloids: total syntheses of preparaherquamide, premalbrancheamide, and (+)-VM-55599

A full account of our studies toward reverse-prenylated indole alkaloids that contain a bicyclo[2.2.2]core is described. A divergent route is reported which has resulted in the synthesis of preparaherquamide, (+)-VM-55599, and premalbrancheamide. An intramolecular Dieckmann cyclization between an en...

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Bibliographic Details
Published in:Chem Sci
Main Authors: Roque, Jose B., Mercado-Marin, Eduardo V., Richter, Sven C., Pereira de Sant'Ana, Danilo, Mukai, Ken, Ye, Yingda, Sarpong, Richmond
Format: Artigo
Language:Inglês
Published: Royal Society of Chemistry 2020
Subjects:
Chemistry
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7480500/
https://ncbi.nlm.nih.gov/pubmed/32953008
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02296a
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