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Homobenzylic Oxygenation Enabled by Dual Organic Photoredox and Cobalt Catalysis

Activation of aliphatic C(sp(3))–H bonds in the presence of more activated benzylic C(sp(3))–H bonds is often a nontrivial, if not impossible task. Herein we show that leveraging the reactivity of benzylic C(sp(3))–H bonds to achieve reactivity at the homobenzylic position can be accomplished using...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: McManus, Joshua B., Griffin, Jeremy D., White, Alexander R., Nicewicz, David A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7476681/
https://ncbi.nlm.nih.gov/pubmed/32459471
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c04422
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