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Unconventional Type III Halogen···Halogen Interactions: A Quantum Mechanical Elucidation of σ-Hole···σ-Hole and Di-σ-Hole Interactions

[Image: see text] Herein, two unconventional type III halogen···halogen interactions, namely, σ-hole···σ-hole and di-σ-hole interactions, were reported in a series of halogenated complexes. In type III, the A-halogen···halogen angles are typically equal to 180°, and the occurrence of σ-hole on halog...

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Publicado en:ACS Omega
Autores principales: Ibrahim, Mahmoud A. A., Moussa, Nayra A. M.
Formato: Artigo
Lenguaje:Inglês
Publicado: American Chemical Society 2020
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC7469378/
https://ncbi.nlm.nih.gov/pubmed/32905309
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.0c02887
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