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Tweaking the Charge Transfer: Bonding Analysis of Bismuth(III) Complexes with a Flexidentate Phosphane Ligand

[Image: see text] To account for the charge transfer and covalent character in bonding between P and Bi centers, the electronic structures of [P(C(6)H(4)-o-CH(2)SCH(3))(3)BiCl(n)]((3–n)+) (n = 0–3) model species have been investigated computationally. On the basis of this survey a synthetic target c...

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Détails bibliographiques
Publié dans:Inorg Chem
Auteurs principaux: Mokrai, Réka, Barrett, Jamie, Apperley, David C., Benkő, Zoltán, Heift, Dominikus
Format: Artigo
Langue:Inglês
Publié: American Chemical Society 2020
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7467670/
https://ncbi.nlm.nih.gov/pubmed/32530279
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.0c00734
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