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Point-to-Axial Chirality Transmission: A Highly Sensitive Triaryl Chirality Probe for Stereochemical Assignments of Amines

[Image: see text] A readily available stereodynamic and the electronic circular dichroism (ECD)-silent 2,5-di(1-naphthyl)-terephthalaldehyde-based probe has been applied for chirality sensing of primary amines. The chiral amine (the inductor) forces a change in the structure of the chromophore syste...

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Publicat a:J Org Chem
Autors principals: Mądry, Tomasz, Czapik, Agnieszka, Kwit, Marcin
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2020
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7458434/
https://ncbi.nlm.nih.gov/pubmed/32806087
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.0c00734
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