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The roles of long-range proton-coupled electron transfer in the directionality and efficiency of [FeFe]-hydrogenases

As paradigms for proton-coupled electron transfer in enzymes and benchmarks for a fully renewable H(2) technology, [FeFe]-hydrogenases behave as highly reversible electrocatalysts when immobilized on an electrode, operating in both catalytic directions with minimal overpotential requirement. Using t...

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Detalhes bibliográficos
Publicado no:Proc Natl Acad Sci U S A
Main Authors: Lampret, Oliver, Duan, Jifu, Hofmann, Eckhard, Winkler, Martin, Armstrong, Fraser A., Happe, Thomas
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7456106/
https://ncbi.nlm.nih.gov/pubmed/32796105
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.2007090117
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