Rhodium(II)-catalyzed multicomponent assembly of α,α,α-trisubstituted esters via formal insertion of O–C(sp(3))–C(sp(2)) into C–C bonds

The direct cleavage of C(CO)−C single bonds, delivering otherwise inaccessible compounds, is a significant challenge. Although the transition metal-catalyzed insertion of functional groups into C(CO)−C bonds has been studied, strained ketone substrates or chelating assistance were commonly required....

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Vydáno v:Nat Commun
Hlavní autoři: Ba, Dan, Wen, Si, Tian, Qingyu, Chen, Yanhui, Lv, Weiwei, Cheng, Guolin
Médium: Artigo
Jazyk:Inglês
Vydáno: Nature Publishing Group UK 2020
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC7445163/
https://ncbi.nlm.nih.gov/pubmed/32839446
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-020-17990-z
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