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Ring expansion of alumoles with organic azides: selective formation of six-membered aluminum–nitrogen heterocycles

Aside from simple Lewis acid–base chemistry, the reaction chemistry of aluminacyclopentadienes, which are commonly referred to as aluminoles or simply alumoles, remains relatively underdeveloped. To date, few attempts to extend their inherent insertion and cycloaddition reactivity to the constructio...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Drescher, Regina, Lin, Shujuan, Hofmann, Alexander, Lenczyk, Carsten, Kachel, Stephanie, Krummenacher, Ivo, Lin, Zhenyang, Braunschweig, Holger
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7444475/
https://ncbi.nlm.nih.gov/pubmed/32874499
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02032j
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