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The role of porphyrin peripheral substituents in determining the reactivities of ferrous nitrosyl species
Ferrous nitrosyl {FeNO}(7) species is an intermediate common to the catalytic cycles of Cd(1)NiR and CcNiR, two heme-based nitrite reductases (NiR), and its reactivity varies dramatically in these enzymes. The former reduces NO(2)(–) to NO in the denitrification pathway while the latter reduces NO(2...
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| 出版年: | Chem Sci |
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| 主要な著者: | , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
Royal Society of Chemistry
2020
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7407271/ https://ncbi.nlm.nih.gov/pubmed/32832056 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc01625j |
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