[Pd(NHC)(μ-Cl)Cl](2): Versatile and Highly Reactive Complexes for Cross-Coupling Reactions that Avoid Formation of Inactive Pd(I) Off-Cycle Products

The development of more reactive, general, easily accessible, and readily available Pd(II)–NHC precatalysts remains a key challenge in homogeneous catalysis. In this study, we establish air-stable NHC–Pd(II) chloro-dimers, [Pd(NHC)(μ-Cl)Cl](2), as the most reactive Pd(II)–NHC catalysts developed to...

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Vydáno v:iScience
Hlavní autoři: Zhou, Tongliang, Ma, Siyue, Nahra, Fady, Obled, Alan M.C., Poater, Albert, Cavallo, Luigi, Cazin, Catherine S.J., Nolan, Steven P., Szostak, Michal
Médium: Artigo
Jazyk:Inglês
Vydáno: Elsevier 2020
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Article
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC7404551/
https://ncbi.nlm.nih.gov/pubmed/32759055
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.isci.2020.101377
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