[FeFe]-hydrogenase maturation: H-cluster assembly intermediates tracked by electron paramagnetic resonance, infrared, and X-ray absorption spectroscopy

ABSTRACT: [FeFe]-hydrogenase enzymes employ a unique organometallic cofactor for efficient and reversible hydrogen conversion. This so-called H-cluster consists of a [4Fe–4S] cubane cysteine linked to a diiron complex coordinated by carbon monoxide and cyanide ligands and an azadithiolate ligand (ad...

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Détails bibliographiques
Publié dans:J Biol Inorg Chem
Auteurs principaux: Németh, Brigitta, Senger, Moritz, Redman, Holly J., Ceccaldi, Pierre, Broderick, Joan, Magnuson, Ann, Stripp, Sven T., Haumann, Michael, Berggren, Gustav
Format: Artigo
Langue:Inglês
Publié: Springer Berlin Heidelberg 2020
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Original Paper
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7399679/
https://ncbi.nlm.nih.gov/pubmed/32661785
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00775-020-01799-8
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