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Modulation of the Self‐Assembly of π‐Amphiphiles in Water from Enthalpy‐ to Entropy‐Driven by Enwrapping Substituents

Depending on the connectivity of solubilizing oligoethylene glycol (OEG) side chains to the π‐cores of amphiphilic naphthalene and perylene bisimide dyes, self‐assembly in water occurs either upon heating or cooling. Herein, we show that this effect originates from differences in the enwrapping capa...

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Publicat a:Chemistry
Autors principals: Syamala, Pradeep P. N., Würthner, Frank
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2020
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7384034/
https://ncbi.nlm.nih.gov/pubmed/32364616
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000995
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