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Highly Oxidized States of Phthalocyaninato Terbium(III) Multiple‐Decker Complexes Showing Structural Deformations, Biradical Properties and Decreases in Magnetic Anisotropy

Presented here is a comprehensive study of highly oxidized multiple‐decker complexes composed of Tb(III) and Cd(II) ions and two to five phthalocyaninato ligands, which are stabilized by electron‐donating n‐butoxy groups. From X‐ray structural analyses, all the complexes become axially compressed up...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Horii, Yoji, Damjanović, Marko, Ajayakumar, M. R., Katoh, Keiichi, Kitagawa, Yasutaka, Chibotaru, Liviu, Ungur, Liviu, Mas‐Torrent, Marta, Wernsdorfer, Wolfgang, Breedlove, Brian K., Enders, Markus, Veciana, Jaume, Yamashita, Masahiro
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7384013/
https://ncbi.nlm.nih.gov/pubmed/32428358
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202001365
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