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Synthesis of a Molecule with Five Different Adjacent Pnictogens

The first molecular compound with all five pnictogens was obtained by a multi‐step reaction. Lithiation of the (bisamido)diazadiarsetidine (tBuNAs)(2)(tBuNH)(2) in aliphatic solvents leads to the dimeric metallated species [(tBuNAs)(2)(tBuNLi)(2)](2) (1(2)). Upon reactions with AsCl(3), SbCl(3) and...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Ritter, Christian, Weigend, Florian, von Hänisch, Carsten
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7383748/
https://ncbi.nlm.nih.gov/pubmed/32428313
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202002279
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