Probing Relaxation Dynamics in Five‐Coordinate Dysprosium Single‐Molecule Magnets

A new family of five‐coordinate lanthanide single‐molecule magnets (Ln SMMs) [Dy(Mes*O)(2)(THF)(2)X] (Mes*=2,4,6‐tri‐tert‐butylphenyl; X=Cl, 1; Br, 2; I, 3) is reported with energy barriers to magnetic reversal >1200 K. The five‐coordinate Dy(III) ions have distorted square pyramidal geometries,...

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Publicado en:Chemistry
Autores principales: Parmar, Vijay S., Ortu, Fabrizio, Ma, Xiaozhou, Chilton, Nicholas F., Clérac, Rodolphe, Mills, David P., Winpenny, Richard E. P.
Formato: Artigo
Lenguaje:Inglês
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC7383731/
https://ncbi.nlm.nih.gov/pubmed/32216105
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202001235
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