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On the Reciprocal Relationship Between σ-Hole Bonding and (Anti)aromaticity Gain in Ketocyclopolyenes
σ-Hole bonding interactions (e.g., tetrel, pnictogen, chalcogen, and halogen bonding) can polarize π-electrons to enhance cyclic [4n] π-electron delocalization (i.e., antiaromaticity gain) or cyclic [4n+2] π-electron delocalization (i.e., aromaticity gain). Examples based on the ketocyclopolyenes: c...
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| Publicado no: | Org Biomol Chem |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7376970/ https://ncbi.nlm.nih.gov/pubmed/32601633 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0ob01076f |
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