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Synthesis of Ir(III) Hydrido Complexes by Oxidative Addition of Halogenated Theophylline and Adenine Derivatives
[Image: see text] The Ir(III) hydrido complexes [1] and [2] have been synthesized by the regioselective oxidative addition of the N7–H bond of 8-halogenotheophyllines to [IrCl(coe)(2)](2) in the presence of PPh(3). The use of dppf in this reaction yielded the bimetallic Ir(III)/Fe(II) hydrido comple...
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| Published in: | ACS Omega |
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| Main Authors: | , , , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
American Chemical Society
2020
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| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7366355/ https://ncbi.nlm.nih.gov/pubmed/32685865 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.0c02290 |
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