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Thermodynamic Hydricity of Small Borane Clusters and Polyhedral closo-Boranes †
Thermodynamic hydricity (HDA(MeCN)) determined as Gibbs free energy (ΔG°[H](−)) of the H(−) detachment reaction in acetonitrile (MeCN) was assessed for 144 small borane clusters (up to 5 boron atoms), polyhedral closo-boranes dianions [B(n)H(n)](2−), and their lithium salts Li(2)[B(n)H(n)] (n = 5–17...
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| Publicado en: | Molecules |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
MDPI
2020
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7357072/ https://ncbi.nlm.nih.gov/pubmed/32630429 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules25122920 |
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