Azidophosphonium salt-directed chemoselective synthesis of (E)/(Z)-cinnamyl-1H-triazoles and regiospecific access to bromomethylcoumarins from Morita–Baylis–Hillman adducts

The direct transformation of Morita–Baylis–Hillman (MBH) adducts into molecules of interest is a crucial process wherein allylic hydroxy-protected or halogenated MBH adducts are commonly preferred. Herein, we report an azidophosphonium salt (AzPS)-catalysed straight forward protocol for synthesising...

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Veröffentlicht in:Beilstein J Org Chem
Hauptverfasser: Karthikeyan, Soundararajan, Shobana, Radha Krishnan, Subimol, Kamarajapurathu Raju, Monica, J Helen Ratna, Kumar, Ayyanoth Karthik Krishna
Format: Artigo
Sprache:Inglês
Veröffentlicht: Beilstein-Institut 2020
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Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7356223/
https://ncbi.nlm.nih.gov/pubmed/32704324
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.16.130
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