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Kinetics and Mechanism of Cation‐Induced Guest Release from Cucurbit[7]uril

The release of two organic guests from cucurbit[7]uril (CB7) was selectively monitored by the stopped‐flow method in aqueous solutions of inorganic salts to reveal the mechanistic picture in detail. Two contrasting mechanisms were identified: The symmetric dicationic 2,7‐dimethyldiazapyrenium shows...

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發表在:Chemistry
Main Authors: Miskolczy, Zsombor, Megyesi, Mónika, Biczók, László, Prabodh, Amrutha, Biedermann, Frank
格式: Artigo
語言:Inglês
出版: John Wiley and Sons Inc. 2020
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC7318709/
https://ncbi.nlm.nih.gov/pubmed/31943402
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201905633
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