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Kinetics and Mechanism of Cation‐Induced Guest Release from Cucurbit[7]uril
The release of two organic guests from cucurbit[7]uril (CB7) was selectively monitored by the stopped‐flow method in aqueous solutions of inorganic salts to reveal the mechanistic picture in detail. Two contrasting mechanisms were identified: The symmetric dicationic 2,7‐dimethyldiazapyrenium shows...
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| Pubblicato in: | Chemistry |
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| Autori principali: | , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
John Wiley and Sons Inc.
2020
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7318709/ https://ncbi.nlm.nih.gov/pubmed/31943402 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201905633 |
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