On the Role of Symmetry in Vibrational Strong Coupling: The Case of Charge‐Transfer Complexation

It is well known that symmetry plays a key role in chemical reactivity. Here we explore its role in vibrational strong coupling (VSC) for a charge‐transfer (CT) complexation reaction. By studying the trimethylated‐benzene–I(2) CT complex, we find that VSC induces large changes in the equilibrium con...

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Vydáno v:Angew Chem Int Ed Engl
Hlavní autoři: Pang, Yantao, Thomas, Anoop, Nagarajan, Kalaivanan, Vergauwe, Robrecht M. A., Joseph, Kripa, Patrahau, Bianca, Wang, Kuidong, Genet, Cyriaque, Ebbesen, Thomas W.
Médium: Artigo
Jazyk:Inglês
Vydáno: John Wiley and Sons Inc. 2020
Témata:
Communications
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC7318350/
https://ncbi.nlm.nih.gov/pubmed/32220038
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202002527
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