Face‐Fusion of Icosahedral Boron Hydride Increases Affinity to γ‐Cyclodextrin: closo,closo‐[B(21)H(18)](−) as an Anion with Very Low Free Energy of Dehydration

The supramolecular recognition of closo,closo‐[B(21)H(18)](−) by cyclodextrins (CDs) has been studied in aqueous solution by isothermal titration calorimetry and nuclear magnetic resonance spectroscopy. These solution studies follow up on previous mass‐spectrometric measurements and computations, wh...

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Detalhes bibliográficos
Publicado no:Chemphyschem
Main Authors: Assaf, Khaleel I., Holub, Josef, Bernhardt, Eduard, Oliva‐Enrich, Josep M., Fernández Pérez, M. Isabel, Canle, Moisés, Santaballa, J. Arturo, Fanfrlík, Jindřich, Hnyk, Drahomír, Nau, Werner M.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7318346/
https://ncbi.nlm.nih.gov/pubmed/32163219
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cphc.201901225
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