Spin Crossover and Long‐Lived Excited States in a Reduced Molecular Ruby

The chromium(III) complex [Cr(III)(ddpd)(2)](3+) (molecular ruby; ddpd=N,N′‐dimethyl‐N,N′‐dipyridine‐2‐yl‐pyridine‐2,6‐diamine) is reduced to the genuine chromium(II) complex [Cr(II)(ddpd)(2)](2+) with d(4) electron configuration. This reduced molecular ruby represents one of the very few chromium(I...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Becker, Patrick M., Förster, Christoph, Carrella, Luca M., Boden, Pit, Hunger, David, van Slageren, Joris, Gerhards, Markus, Rentschler, Eva, Heinze, Katja
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7318154/
https://ncbi.nlm.nih.gov/pubmed/32167607
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202001237
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