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Synthesis and Application of a Perfluorinated Ammoniumyl Radical Cation as a Very Strong Deelectronator
The perfluorinated dihydrophenazine derivative (perfluoro‐5,10‐bis(perfluorophenyl)‐5,10‐dihydrophenazine) (“phenazine(F)”) can be easily transformed to a stable and weighable radical cation salt by deelectronation (i.e. oxidation) with Ag[Al(OR(F))(4)]/ Br(2) mixtures (R(F)=C(CF(3))(3)). As an inno...
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| Veröffentlicht in: | Angew Chem Int Ed Engl |
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| Hauptverfasser: | , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
John Wiley and Sons Inc.
2020
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7317951/ https://ncbi.nlm.nih.gov/pubmed/32187797 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202002768 |
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