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Scope and Limitations of the s‐Block Metal‐Mediated Pudovik Reaction
The hydrophosphorylation of phenylacetylene with di(aryl)phosphane oxides Ar(2)P(O)H (Pudovik reaction) yields E/Z‐isomer mixtures of phenylethenyl‐di(aryl)phosphane oxides (1). Alkali and alkaline‐earth metal di(aryl)phosphinites have been studied as catalysts for this reaction with increasing acti...
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| Publicado no: | Chemistry |
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| Principais autores: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7317549/ https://ncbi.nlm.nih.gov/pubmed/32027050 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201905565 |
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