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Synthesis of a Counteranion‐Stabilized Bis(silylium) Ion

The preparation of a molecule with two alkyl‐tethered silylium‐ion sites from the corresponding bis(hydrosilanes) by two‐fold hydride abstraction is reported. The length of the conformationally flexible alkyl bridge is crucial as otherwise the hydride abstraction stops at the stage of a cyclic bissi...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Wu, Qian, Roy, Avijit, Wang, Guoqiang, Irran, Elisabeth, Klare, Hendrik F. T., Oestreich, Martin
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7317492/
https://ncbi.nlm.nih.gov/pubmed/32216163
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202003799
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