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Formal C−H Carboxylation of Unactivated Arenes

A formal C−H carboxylation of unactivated arenes using CO(2) in green solvents is described. The present strategy combines a sterically controlled Ir‐catalyzed C−H borylation followed by a Cu‐catalyzed carboxylation of the in situ generated organoboronates. The reaction is highly regioselective for...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Gevorgyan, Ashot, Hopmann, Kathrin H., Bayer, Annette
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7317471/
https://ncbi.nlm.nih.gov/pubmed/32003869
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000515
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