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An Extensive Set of Accurate Fluoride Ion Affinities for p‐Block Element Lewis Acids and Basic Design Principles for Strong Fluoride Ion Acceptors

The computed fluoride ion affinity (FIA) is a valuable descriptor to assess the Lewis acidity of a compound. Despite its widespread use, the varying accuracy of applied computational models hampers the broad comparability of literature data. Herein, we evaluate the performance of selected methods (l...

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Veröffentlicht in:Chemphyschem
Hauptverfasser: Erdmann, Philipp, Leitner, Jonas, Schwarz, Julia, Greb, Lutz
Format: Artigo
Sprache:Inglês
Veröffentlicht: John Wiley and Sons Inc. 2020
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7317340/
https://ncbi.nlm.nih.gov/pubmed/32212357
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cphc.202000244
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