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Cooperative Carbon Dioxide Adsorption in Alcoholamine- and Alkoxyalkylamine-Functionalized Metal–Organic Frameworks

A series of structurally diverse alcoholamine- and alkoxyalkylamine-functionalized variants of the metal–organic framework Mg(2)(dobpdc) are shown to adsorb CO(2) selectively via cooperative chain-forming mechanisms. Solid-state NMR spectra and optimized structures obtained from van der Waals-correc...

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Publicado en:Angew Chem Int Ed Engl
Main Authors: Mao, Victor Y., Milner, Phillip J., Lee, Jung-Hoon, Forse, Alexander C., Kim, Eugene J., Siegelman, Rebecca L., McGuirk, C. Michael, Porter-Zasada, Leo B., Neaton, Jeffrey B., Reimer, Jeffrey A., Long, Jeffrey R.
Formato: Artigo
Idioma:Inglês
Publicado: 2020
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC7316600/
https://ncbi.nlm.nih.gov/pubmed/31880046
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201915561
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