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Controlling J-Aggregates Formation and Chirality Induction through Demetallation of a Zinc(II) Water Soluble Porphyrin

Under acidic conditions and at high ionic strength, the zinc cation is removed from its metal complex with 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin (TPPS(4)) thus leading to the diacid free porphyrin, that subsequently self-organize into J-aggregates. The kinetics of the demetallation step an...

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Bibliographic Details
Published in:Int J Mol Sci
Main Authors: Occhiuto, Ilaria Giuseppina, Castriciano, Maria Angela, Trapani, Mariachiara, Zagami, Roberto, Romeo, Andrea, Pasternack, Robert F., Monsù Scolaro, Luigi
Format: Artigo
Language:Inglês
Published: MDPI 2020
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7313071/
https://ncbi.nlm.nih.gov/pubmed/32503280
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/ijms21114001
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